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Chemija / Chemistry

ISSN 0235-7216
ISSN 2424-4538 (online)

2008 m. Nr. 3-4

Peculiarities of b-cyclodextrin acid hydrolysis
Rimantas VAITKUS, Giedrė GRINCIENĖ, Eugenijus NORKUS

Acidic hydrolysis of β-cyclodextrin in acetic acid solutions was investigated. It was found from kinetic observations and reverse kinetic isotope effect that the reaction proceeded according to the mechanism of specific acid catalysis. Investigation of cyclodextrin hydrolysis in the presence of some aromatic and aliphatic compounds was carried out. The rate of the reaction was found to decrease with an increase in the concentration of a guest.

Keywords: acidic hydrolysis, β-cyclodextrin, inclusion complex

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